Mukotsu was a member of the Band of Seven, a group of ruthless bandits resurrected by Naraku. He specialized in using various dangerous poisons (which appeared to affect only humans). Despite his cunning nature, he was deeply insecure about his face's ugliness, claiming it caused all women to hate him.
Spoiler
He was killed by Sesshomaru simply because he got in Sesshomaru's way.
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