Shiemi is Rin's classmate and friend. Before meeting Rin, she tended her grandmother's garden while her mother ran an Exorcist-only shop within True Cross Academy. During her encounter with Rin and Yukio, they discovered that a Demon was leaching Shiemi's life force. After Yukio exorcised the demon, Shiemi decided to become an Exorcist and began attending classes. It was later revealed that Shiemi possessed talent as a Tamer, evidenced by her ability to summon a Greenman Spirit during class. This is apparently a rare talent among Exorcists, as only a few can control demons and fight.
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