She serves as the chief interrogator and executioner for the Church Investigation Commission, having arrived in the human realm from Ente Isla to investigate reports regarding Emi's alliance with Maou. Unaware of her identity, Maou finds her becoming his next-door neighbor; they eventually grow close, and she frequently visits his apartment to cook meals for everyone, given her skill in the kitchen. She knows very little about the human realm, particularly Tokyo, which makes navigating the city and understanding people's fashion sense difficult for her.
Spoiler
It seems, from the start, that Maou and Lucifer knew who she was.
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