Piyoko is eight years old. She serves as the Princess of planet Analogue and leads the Black Gema Gema Gang. Her parents left her in the care of Rik, Ky, and Coo until she turns thirteen, as they are too embarrassed to show their faces following their failed attempt to take over planet Di Gi Charat. She was forced to flee to Earth after blowing up a city and being unable to pay for the repairs. Piyoko dresses in an outfit resembling a nurse's uniform, colored black and white like a panda. She ends her sentences with "pyo". She possesses an attack similar to Dejiko's Laser Eye Beam called the Upchuck Bazooka, which is a beam fired from her mouth; however, whenever she attempts to attack Dejiko with it, she more often than not gets attacked herself. Piyoko makes a brief cameo in Episode 2 of Cromartie High School, appearing as a teenage version of herself.
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